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A cellphone-based colorimetric multi-channel sensor for water environmental monitoring

《环境科学与工程前沿(英文)》 2022年 第16卷 第12期 doi: 10.1007/s11783-022-1590-z

摘要:

● A cellphone-based colorimetric multi-channel sensor for in-field detection.

关键词: Colorimetric analysis     Multi-channel sensor     Cellphone     Water quality indexes     Environmental monitoring    

Label-free colorimetric nanosensor with improved sensitivity for Pb

Abdul Ghaffar Memon, Xiaohong Zhou, Yunpeng Xing, Ruoyu Wang, Lanhua Liu, Mohsin Khan, Miao He

《环境科学与工程前沿(英文)》 2019年 第13卷 第1期 doi: 10.1007/s11783-019-1094-7

摘要:

• Unmodified-AuNP based, colorimetric nanosensor was constructed for Pb2+ detection.

• 5-nucleotide truncation in DNAzyme made complete substrate detachment upon Pb2+.

• Ultrasensitive and selective detection of Lead (II) was achieved with 0.2×10-9 mol/L LOD.

关键词: Colorimetric nanosensor     Truncated 8–17 DNAzyme     Pb2+ detection     Unmodified AuNPs    

Biomineralization-inspired copper-cystine nanoleaves capable of laccase-like catalysis for the colorimetric

Miao Guan, Mengfan Wang, Wei Qi, Rongxin Su, Zhimin He

《化学科学与工程前沿(英文)》 2021年 第15卷 第2期   页码 310-318 doi: 10.1007/s11705-020-1940-y

摘要: Recently, many efforts have been dedicated to creating enzyme-mimicking catalysts to replace natural enzymes in practical fields. Inspired by the pathological biomineralization behaviour of L-cystine, in this study, we constructed a laccase-like catalyst through the co-assembly of L-cystine with Cu ions. Structural analysis revealed that the formed catalytic Cu-cystine nanoleaves (Cu-Cys NLs) possess a Cu(I)-Cu(II) electron transfer system similar to that in natural laccase. Reaction kinetic studies demonstrated that the catalyst follows the typical Michaelis-Menten model. Compared with natural laccase, the Cu-Cys NLs exhibit superior stability during long-term incubation under extreme pH, high-temperature or high-salt conditions. Remarkably, the Cu-Cys NLs could be easily recovered and still maintained 76% of their activity after 8 cycles. Finally, this laccase mimic was employed to develop a colorimetric method for epinephrine detection, which achieved a wider linear range (9–455 μmol·L ) and lower limit of detection (2.7 μmol·L ). The Cu-Cys NLs also displayed excellent specificity and sensitivity towards epinephrine in a test based on urine samples.

关键词: biomineralization     laccase     L-cystine     colorimetric detection     enzyme mimic    

A novel flavonol-based colorimetric and turn-on fluorescent probe for rapid determination of hydrazine

《化学科学与工程前沿(英文)》 2023年 第17卷 第1期   页码 24-33 doi: 10.1007/s11705-022-2171-1

摘要: Hydrazine is extremely toxic and causes severe harm to human body. Herein, a novel fluorescent probe 4-oxo-2-styryl-4H-chromen-3-yl thiophene-2-carboxylate (FHT) was synthesized for detecting hydrazine by using natural cinnamaldehyde as starting material. This probe exhibited significantly enhanced fluorescence response towards hydrazine over various common metal ions, anions, and amine compounds. The detection limit of probe FHT for hydrazine was as low as 0.14 μmol·L–1, significantly lower than that of the threshold value of 0.312 μmol·L–1, imposed by the Environmental Protection Agency. Moreover, the proposed probe was able to detect hydrazine within wide pH (5–10) and linear detection ranges (0–110 μmol·L–1). This probe was employed for determining trace hydrazine in different environmental water samples. The probe FHT-loaded filter paper strips were able to conveniently detect hydrazine of low concentration through distinct naked-eye and fluorescent color changes. Importantly, the probe FHT with low cytotoxicity was successfully applied to visualize hydrazine in living Hela cells and zebrafish.

关键词: cinnamaldehyde     3-hydroxychromone derivative     hydrazine     fluorescent probe    

A simple, azulene-based colorimetric probe for the detection of nitrite in water

Lloyd C. Murfin, Carlos M. López-Alled, Adam C. Sedgwick, Jannis Wenk, Tony D. James, Simon E. Lewis

《化学科学与工程前沿(英文)》 2020年 第14卷 第1期   页码 90-96 doi: 10.1007/s11705-019-1790-7

摘要: We describe the synthesis and evaluation of an azulene-based chemodosimeter for nitrite. The probe was found to undergo two distinct color changes upon introduction aqueous nitrite ion. A near-instant formation of a grey color provides a qualitative indication of the presence of nitrite, followed by the formation of a deep-yellow/orange color, the endpoint from which quantitative data can be derived. The azulene probe exhibits 1:1 stoichiometry of reaction with nitrite in water, and is selective for nitrite over other anions. The azulene probe was applied to determine nitrite content in cured meat, and compared with the British Standard testing procedure (Griess test). The value obtained from the azulene-based probe agreed closely with the standard test. Our procedure only requires the preparation of one standard solution, instead of the three required for the standard Griess test.

关键词: azulene     nitrite     diazoquinone    

A review of measurement methods for peracetic acid (PAA)

Chen Cheng, Haodong Li, Jinling Wang, Hualin Wang, Xuejing Yang

《环境科学与工程前沿(英文)》 2020年 第14卷 第5期 doi: 10.1007/s11783-020-1266-5

摘要: Abstract • Physical and chemical properties and application of peracetic acid solution. • Determination method of high concentration peracetic acid. • Determination method of residual peracetic acid (low concentration). Peroxyacetic acid has been widely used in food, medical, and synthetic chemical fields for the past several decades. Recently, peroxyacetic acid has gradually become an effective alternative disinfectant in wastewater disinfection and has strong redox capacity for removing micro-pollutants from drinking water. However, commercial peroxyacetic acid solutions are primarily multi-component mixtures of peroxyacetic acid, acetic acid, hydrogen peroxide, and water. During the process of water treatment, peroxyacetic acid and hydrogen peroxide (H2O2) often coexist, which limits further investigation on the properties of peroxyacetic acid. Therefore, analytical methods need to achieve a certain level of selectivity, particularly when peroxyacetic acid and hydrogen peroxide coexist. This review summarizes the measurement and detection methods of peroxyacetic acid, comparing the principle, adaptability, and relative merits of these methods.

关键词: Peroxyacetic acid     Measurement methods     Titration     Colorimetric     Chromatography     NMR    

Anthocyanins/chitosan films doped by nano zinc oxide for active and intelligent packaging: comparison of anthocyanins source from purple tomato or black wolfberry

《化学科学与工程前沿(英文)》 2023年 第17卷 第6期   页码 704-715 doi: 10.1007/s11705-022-2270-z

摘要: The multifunctional films was prepared by blending chitosan and nano-ZnO with purple tomato anthocyanins or black wolfberry anthocyanins. The properties of films functioned by anthocyanins source and nano-ZnO content were studied. It was found purple tomato anthocyanins showed more significant color change against pH than black wolfberry anthocyanins. The nano-ZnO were widely dispersed in matrix and enhanced the compatibility of anthocyanins with chitosan. However, the anthocyanins source influenced the properties of the films more slightly than nano-ZnO addition. The tensile strength, antioxidant and antibacterial effects of the chitosan films dramatically increased after cooperated by nano-ZnO and anthocyanins, which also enhanced with increase of nano-ZnO content, whereas the elongation at break of the composite films decreased. Especially, the anthocyanin and nano-ZnO promoted the antibacterial activity of films synergistically. Composite films made from black wolfberry anthocyanins exhibited higher mechanical performance than those made from purple tomato anthocyanins but weaker antibacterial effects. The purple tomato anthocyanins/chitosan and nano-ZnO/purple tomato anthocyanins/chitosan films effectively reflected pork spoilage, changing their colors from dark green to brown, indicating the potential for applications in active and intelligent food packaging.

关键词: bio-based     multifunction     colorimetric indicator     active and intelligent packaging    

Decomposition analysis applied to energy and emissions: A literature review

《工程管理前沿(英文)》   页码 625-639 doi: 10.1007/s42524-023-0270-4

摘要: Decomposition analysis has been widely used to assess the determinants of energy and CO2 emissions in academic research and policy studies. Both the methodology and application of decomposition analysis have been largely improved in the past decades. After more than 50 years’ developments, decomposition studies have become increasingly sophisticated and diversified, and tend to converge internally and integrate with other analytical approaches externally. A good understanding of the literature and state of the art is critical to identify knowledge gaps and formulate future research agenda. To this end, this study presents a literature survey for decomposition analysis applied to energy and emission issues, with a focus on the period of 2016–2021. A review for three individual decomposition techniques is first conducted, followed by a synthesis of emerging trends and features for the decomposition analysis literature as a whole. The findings are expected to direct future research in decomposition analysis.

关键词: index decomposition analysis     structural decomposition analysis     production decomposition analysis     energy     CO2 emissions    

Flow, thermal, and vibration analysis using three dimensional finite element analysis for a flux reversal

B. VIDHYA,K. N. SRINIVAS

《能源前沿(英文)》 2016年 第10卷 第4期   页码 424-440 doi: 10.1007/s11708-016-0423-9

摘要: This paper presents the simulation of major mechanical properties of a flux reversal generator (FRG) viz., computational fluid dynamic (CFD), thermal, and vibration. A three-dimensional finite element analysis (FEA) based CFD technique for finding the spread of pressure and air velocity in air regions of the FRG is described. The results of CFD are mainly obtained to fine tune the thermal analysis. Thus, in this focus, a flow analysis assisted thermal analysis is presented to predict the steady state temperature distribution inside FRG. The heat transfer coefficient of all the heat producing inner walls of the machine are evaluated from CFD analysis, which forms the main factor for the prediction of accurate heat distribution. The vibration analysis is illustrated. Major vibration sources such as mechanical, magnetic and applied loads are covered elaborately which consists of a 3D modal analysis to find the natural frequency of FRG, a 3D static stress analysis to predict the deformation of the stator, rotor and shaft for different speeds, and an unbalanced rotor harmonic analysis to find eccentricity of rotor to make sure that the vibration of the rotor is within the acceptable limits. Harmonic analysis such as sine sweep analysis to identify the range of speeds causing high vibrations and steady state vibration at a mode frequency of 1500 Hz is presented. The vibration analysis investigates the vibration of the FRG as a whole, which forms the contribution of this paper in the FRG literature.

关键词: flux reversal generator     air velocity     computation fluid dynamics     thermal analysis     vibration analysis     finite element analysis    

Review of sentiment analysis: An emotional product development view

《工程管理前沿(英文)》   页码 592-609 doi: 10.1007/s42524-022-0227-z

摘要: Conveying consumers’ specific emotions in new products, referred to as emotional product development or emotional design, is strategically crucial for manufacturers. Given that sentiment analysis (SA) can extract and analyze people’s opinions, sentiments, attitudes, and perceptions regarding different products/services, SA-based emotional design may provide manufacturers with real-time, direct, and rapid decision support. Despite its considerable advancements and numerous survey and review articles, SA is seldom considered in emotional design. This study is among the first efforts to conduct a thorough review of SA from the view of emotional design. The comprehensive review of aspect-level SA reveals the following: 1) All studies focus on extracting product features by mixing technical product features and consumers’ emotional perceptions. Consequently, such studies cannot capture the relationships between technical and emotional attributes and thus cannot convey specific emotions to the new products. 2) Most studies use the English language in SA, but other languages have recently received more interest in SA. Furthermore, after conceptualizing emotion as Kansei and introducing emotional product development and Kansei Engineering, a review of the data-driven emotional design is then conducted. A few efforts start to study emotional design with the help of SA. However, these studies only focus on either analyzing consumers’ preferences on product features or extracting emotional opinions from online reviews, thus cannot realize data-driven emotional product development. Finally, some research opportunities are provided. This study opens a broad door to aspect-level SA and its integration with emotional product development.

关键词: sentiment analysis     emotion     product development     Kansei Engineering    

Jack up reliability analysis: An overview

Ahmad IDRIS, Indra Sati Hamonangan HARAHAP, Montasir Osman Ahmed ALI

《结构与土木工程前沿(英文)》 2018年 第12卷 第4期   页码 504-514 doi: 10.1007/s11709-017-0443-5

摘要: Jack up is a mobile unit used for oil and gas exploration and production in offshore fields. On demand, the unit is moved and installed in a given location and used for a period up to 12 months before being un-installed and moved to another location. Due to its mobility and re-usability, when the unit is offered for use in a given offshore location, its suitability in terms of safe operation is evaluated in accordance with the guidelines of Site Specific Assessment (SSA) of jack up. When the unit failed safety assessment criteria, the guideline recommended that it is re-assessed by increasing the complexity of the assumptions and methods used. Reliability analysis theories are one of the frameworks recommended for the safety assessment of the units. With recent developments in uncertainty and reliability analysis of structures subject to stochastic excitation, this study aims at providing a review on the past developments in jack up reliability analysis and to identify possible future directions. The results from literature reviewed shows that failure probabilities vary significantly with analysis method used. In addition, from the variants of reliability analysis approach, the method of time dependent reliability for dynamic structures subject to stochastic excitation have not been implemented on jack ups. Consequently, suggestions were made on the areas that need further examination for improvement of the efficiency in safety assessment of the units using reliability theories.

关键词: jack up     reliability analysis     uncertainty analysis     review of jack up    

Systems biomedical analysis of Schistosoma japonicum

Ze-Guang HAN MD,

《医学前沿(英文)》 2010年 第4卷 第2期   页码 157-165 doi: 10.1007/s11684-010-0034-5

摘要: Human schistosomiasis, caused mainly by three principal species including , , and , remains a major public health concern worldwide. is prevalent in southern China, being a major disease risk for 66 million people. The blood fluke has a complex life cycle for survival: as a free-living form in fresh water and as a parasite in the snail intermediate and vertebrate definitive hosts. Systems-based biomedical analyses, including genomic, transcriptomic, proteomic and metabonomic approaches, have been performed on the schistosome. These comprehensive investigations have not only characterized the genomic features but also chartered gene and protein expression profiles across genders and developmental stages. The integration of the huge information will lay a global and solid foundation for the molecular architecture of the biology, pathogenesis, and host-parasite interactions of the human blood fluke, which will facilitate the development of a new antischistosomal vaccine and drugs as well as diagnostic markers for the treatment and control of schistosomiasis.

关键词: Schistosoma japonicum     systems biomedical analysis    

Numerical analysis and experimental investigation of modal properties for the gearbox in wind turbine

Pengxing YI,Peng HUANG,Tielin SHI

《机械工程前沿(英文)》 2016年 第11卷 第4期   页码 388-402 doi: 10.1007/s11465-016-0404-z

摘要:

Wind turbine gearbox (WTG), which functions as an accelerator, ensures the performance and service life of wind turbine systems. This paper examines the distinctive modal properties of WTGs through finite element (FE) and experimental modal analyses. The study is performed in two parts. First, a whole system model is developed to investigate the first 10 modal frequencies and mode shapes of WTG using flexible multi-body modeling techniques. Given the complex structure and operating conditions of WTG, this study applies spring elements to the model and quantifies how the bearings and gear pair interactions affect the dynamic characteristics of WTGs. Second, the FE modal results are validated through experimental modal analyses of a 1.5 WM WTG using the frequency response function method of single point excitation and multi-point response. The natural frequencies from the FE and experimental modal analyses show favorable agreement and reveal that the characteristic frequency of the studied gearbox avoids its eigen-frequency very well.

关键词: wind turbine gearbox     modal analysis     finite element analysis     modal frequency     bearing equivalence    

Isogeometric analysis of coupled thermo-elastodynamic problems under cyclic thermal shock

Asghar AMANI DASHLEJEH

《结构与土木工程前沿(英文)》 2019年 第13卷 第2期   页码 397-405 doi: 10.1007/s11709-018-0473-7

摘要: The isogeometric analysis (IGA) method was extended for the solution of the coupled thermo-elastodynamic equations. The dimensionless formulation was accepted in discretization of the uncoupled and coupled thermoelasticity equations and the Generalized Newmark method was used in the time integration procedure. First, the performance of the proposed method was verified against a two-dimensional benchmark example subjected to constant thermal shock with available exact analytical solutions. Then a two-dimensional half-space benchmark example under thermal shock was solved. Finally, cyclic thermal shock (CTS) loading was applied on the half-space problem. The results dedicated that IGA can be used as a suitable approach in the analysis of the general thermomechanical problems.

关键词: isogeometric analysis     coupled thermo-elastodynamic     dynamic analysis     generalized newmark     cyclic thermal shock    

A dimensional analysis on asphalt binder fracture and fatigue cracking

Qian ZHAO, Zhoujing YE

《结构与土木工程前沿(英文)》 2018年 第12卷 第2期   页码 201-206 doi: 10.1007/s11709-017-0402-1

摘要: Fracture and fatigue cracking in asphalt binder are two of most serious problems for pavement engineers. In this paper, we present a new comprehensive approach, which consists both of dimensional analysis using Buckingham Theorem and -integral analysis based on classic fracture mechanics, to evaluate the fracture and fatigue on asphalt binder. It is discovered that the dimensional analysis could provide a new perspective to analyze the asphalt fracture and fatigue cracking mechanism.

关键词: Dimensional analysis     asphalt     fracture     fatigue cracking    

标题 作者 时间 类型 操作

A cellphone-based colorimetric multi-channel sensor for water environmental monitoring

期刊论文

Label-free colorimetric nanosensor with improved sensitivity for Pb

Abdul Ghaffar Memon, Xiaohong Zhou, Yunpeng Xing, Ruoyu Wang, Lanhua Liu, Mohsin Khan, Miao He

期刊论文

Biomineralization-inspired copper-cystine nanoleaves capable of laccase-like catalysis for the colorimetric

Miao Guan, Mengfan Wang, Wei Qi, Rongxin Su, Zhimin He

期刊论文

A novel flavonol-based colorimetric and turn-on fluorescent probe for rapid determination of hydrazine

期刊论文

A simple, azulene-based colorimetric probe for the detection of nitrite in water

Lloyd C. Murfin, Carlos M. López-Alled, Adam C. Sedgwick, Jannis Wenk, Tony D. James, Simon E. Lewis

期刊论文

A review of measurement methods for peracetic acid (PAA)

Chen Cheng, Haodong Li, Jinling Wang, Hualin Wang, Xuejing Yang

期刊论文

Anthocyanins/chitosan films doped by nano zinc oxide for active and intelligent packaging: comparison of anthocyanins source from purple tomato or black wolfberry

期刊论文

Decomposition analysis applied to energy and emissions: A literature review

期刊论文

Flow, thermal, and vibration analysis using three dimensional finite element analysis for a flux reversal

B. VIDHYA,K. N. SRINIVAS

期刊论文

Review of sentiment analysis: An emotional product development view

期刊论文

Jack up reliability analysis: An overview

Ahmad IDRIS, Indra Sati Hamonangan HARAHAP, Montasir Osman Ahmed ALI

期刊论文

Systems biomedical analysis of Schistosoma japonicum

Ze-Guang HAN MD,

期刊论文

Numerical analysis and experimental investigation of modal properties for the gearbox in wind turbine

Pengxing YI,Peng HUANG,Tielin SHI

期刊论文

Isogeometric analysis of coupled thermo-elastodynamic problems under cyclic thermal shock

Asghar AMANI DASHLEJEH

期刊论文

A dimensional analysis on asphalt binder fracture and fatigue cracking

Qian ZHAO, Zhoujing YE

期刊论文